:: 글답변 ::
Author
Password
E-mail
Homepage
Option
html
Topic
> > > http://geology.com/energy/hydraulic-fracturing-fluids/ > > > Hydraulic Fracturing Fluids - Composition and Additives > Republished from: Modern Shale Gas Development in the United States by the U.S. Department of Energy. > > What is Hydraulic Fracturing? > > The current practice for hydraulic fracture treatments of shale gas reservoirs is to apply a sequenced pumping event in which millions of gallons of water-based fracturing fluids mixed with proppant materials are pumped in a controlled and monitored manner into the target shale formation above fracture pressure [1]. > > > Hydraulic Fracturing Additives > > The fracturing fluids used for gas shale stimulations consist primarily of water but also include a variety of additives. The number of chemical additives used in a typical fracture treatment varies depending on the conditions of the specific well being fractured. > > A typical fracture treatment will use very low concentrations of between 3 and 12 additive chemicals depending on the characteristics of the water and the shale formation being fractured. Each component serves a specific, engineered purpose [2]). > > > Friction Reducing (Slickwater) Additives > > The predominant fluids currently being used for fracture treatments in the gas shale plays are water-based fracturing fluids mixed with friction-reducing additives (called slickwater) [3]. The addition of friction reducers allows fracturing fluids and proppant to be pumped to the target zone at a higher rate and reduced pressure than if water alone were used. > > > Other Additives and Proppants > > In addition to friction reducers, other additives include: biocides to prevent microorganism growth and to reduce biofouling of the fractures; oxygen scavengers and other stabilizers to prevent corrosion of metal pipes; and acids that are used to remove drilling mud damage within the near-wellbore area [4]. These fluids are used not only to create the fractures in the formation but also to carry a propping agent (typically silica sand) which is deposited in the induced fractures. > > The make-up of fracturing fluid varies from one geologic basin or formation to another. A list of potential additives is given in Table 1 [5]. Evaluating the relative volumes of the components of a fracturing fluid reveals the relatively small volume of additives that are present. Overall the concentration of additives in most slickwater fracturing fluids is a relatively consistent 0.5% to 2% with water making up 98% to 99.5%. > > > Fracturing Fluids Vary from One Play to Another > > Ads by Google > > Valuate Oil/Gas Property > Our Software Helps you Analyze and Obtain Property Valuations > www.slb.com/Schlumberger > > Unconventional Gas Center > Marcellus Oil And Gas Daily Newsletter, Maps & More > UGCenter.com/Shales/US/Marcellus/ > > Because the make-up of each fracturing fluid varies to meet the specific needs of each area, there is no one-size-fits-all formula for the volumes for each additive. In classifying fracturing fluids and their additives it is important to realize that service companies that provide these additives have developed a number of compounds with similar functional properties to be used for the same purpose in different well environments. > > The difference between additive formulations may be as small as a change in concentration of a specific compound. Although the hydraulic fracturing industry may have a number of compounds that can be used in a hydraulic fracturing fluid, any single fracturing job would only use a few of the available additives. It is not uncommon for some fracturing recipes to omit some compound categories if their properties are not required for the specific application. > > Most industrial processes use chemicals and almost any chemical can be hazardous in large enough quantities or if not handled properly. Even chemicals that go into our food or drinking water can be hazardous. For example, drinking water treatment plants use large quantities of chlorine. When used and handled properly, it is safe for workers and near-by residents and provides clean, safe drinking water for the community. > > Although the risk is low, the potential exists for unplanned releases that could have serious effects on human health and the environment. By the same token, hydraulic fracturing uses a number of chemical additives that could be hazardous, but are safe when properly handled according to requirements and long-standing industry practices. In addition, many of these additives are common chemicals which people regularly encounter in everyday life. > > > Dilution and Neutralization of Additives > > > Types of Volcanic Eruptions > Diamonds Don't Form From Coal > What is a Debris Flow? > The Only Diamond Mine in the USA > > Table 1 provides a summary of the additives, their main compounds, the reason the additive is used in a hydraulic fracturing fluid, and some of the other common uses for these compounds. Hydrochloric acid (HCl) is the single largest liquid component used in a fracturing fluid aside from water; while the concentration of the acid may vary, a 15% HCl mix is a typical concentration. A 15% HCl mix is composed of 85% water and 15% acid, therefore, the volume of acid is diluted by 85% with water in its stock solution before it is pumped into the formation during a fracturing treatment. > > Once the entire stage of fracturing fluid has been injected, the total volume of acid in an example fracturing fluid from the Fayetteville shale was 0.123%, which indicates the fluid had been diluted by a factor of 122 times before it is pumped into the formation. The concentration of this acid will only continue to be diluted as it is further dispersed in additional volumes of water that may be present in the subsurface. Furthermore, if this acid comes into contact with carbonate minerals in the subsurface, it would be neutralized by chemical reaction with the carbonate minerals producing water and carbon dioxide as a byproduct of the reaction. > > > > This video illustrates the equipment, materials and procedures used in the hydraulic fracturing process. It applies to the use of hydraulic fracturing combined with horizontal drilling in the development of a natural gas well in an organic-rich shale. It was prepared by Chesapeake Energy. > > > > 50Share > > A wide variety of chemical additives are used in hydraulic fracturing fluids. They include: dilute acids, biocides, breakers, corrosion inhibitors, crosslinkers, friction reducers, gels, potassium chloride, oxygen scavengers, pH adjusting agents, scale inhibitors and surfactants. These chemical additives typically might make up just 1/2 to 2 percent of the fluid. The remaining 98 to 99 1/2 percent of the fluid is water. Proppants such as sand, aluminum shot or ceramic beads are frequently injected to hold fractures open after the pressure treatment is completed. > > > Ads by Google > > Sell Your Mineral Rights > We Buy Mineral Rights Nationwide! Contact Us for a Free Bid Estimate > www.sequoiaroyalty.com > > Oil and Gas Investments > Large Ownership. Small Investment Direct Partnership. Now Funding > oilandgasinvestment.com > > We buy Minerals & Royalty > Cash for oil and gas interests Simple and Fast > www.clearforkroyalty.com > > Municipal Bonds Prices > Search for bonds by State, Maturity & Credit at RBC Wealth Management > www.RBCBondsearch.com > > > Hydraulic Fracturing in the News > A Huge Demand for High Quality Frack Sand: A small number of mines can produce the... > > Orange Peel Extract as a Hydraulic Fracturing Fluid?: A well service company has a patented hydraulic... > > Arkansas: Waste Water Injection and Earthquakes: An injection well used to dispose of waste... > > Expert Panel has 90 Days to Make Fracking Cleaner and Safer: Natural gas is a key factor in our... > > Should France Ban Shale Gas Development?: People in France are concerned about the potential... > > Manufacturing Oil and Gas Reservoirs in the Niobrara Shale: Mark Northam, director of the School of Energy... > > Foreign Ownership of United States Gas Shales: A letter published in The Ithaca Journal complains... > > Natural Gas Drilling and Radiation in Water Supplies: An article in The Texas Tribune explores the... > > Marcellus Shale Economic Impact in West Virginia: A study on the economic, legal, regulatory, and... > > Shale Gas Drillers Switching to Shale Oil: To improve their income many natural gas companies... > > > Daily news delivered to you free by RSS or email. > > > Information Sources > [1] Harper, J. 2008. The Marcellus Shale – An Old "New" Gas Reservoir in Pennsylvania. Pennsylvania Geology. v 28, no 1. Spring 2008. Published by the Bureau of Topographic and Geologic Survey, Pennsylvania Department of Conservation and Natural Resources. > > [2] Schlumberger. Fracturing. http://www.slb.com/services/stimulation/reservoir.aspx Accessed: September 2008. > > [3] Ketter, A.A., J. L. Daniels, J. R. Heinze, and G. Waters. A Field Study Optimizing Completion Strategies for Fracture Initiation in Barnett Shale Horizontal Wells. SPE 103232. > > [4] Schlumberger. PowerSTIM. http://www.slb.com/services/stimulation/execution/ well_optimization.aspx Accessed: September 2008. > > [5] Modified from: Arthur, J.D., B. Bohm, and M. Layne. 2008. ALL Consulting. Hydraulic Fracturing Considerations for Natural Gas Wells of the Marcellus Shale. Presented at the GWPC Annual Forum in Cincinnati, OH. September 2008. > > [6] U.S. Department of Energy, (2009). Modern Shale Gas Development in the United States: A Primer. Work Performed Under DE-FG26-04NT15455. Prepared by The Ground Water Protection Council and ALL Consulting. > > > > Marcellus Shale Gas Play > Haynesville Shale Gas Play > Natural Gas News > Natural Gas Royalty Calculator > Barnett Shale Natural Gas > Natural Gas Shales > What is Shale? > Hydraulic Fracturing > Horizontal Drilling > > > Fracturing Fluid Additives > Additive Type Main Compound(s) Purpose Common Use of Main Compound > Diluted Acid (15%) Hydrochloric acid or muriatic acid Help dissolve minerals and initiate cracks in the rock Swimming pool chemical and cleaner > Biocide Glutaraldehyde Eliminates bacteria in the water that produce corrosive byproducts Disinfectant; sterilize medical and dental equipment > Breaker Ammonium persulfate Allows a delayed break down of the gel polymer chains Bleaching agent in detergent and hair cosmetics, manufacture of household plastics > Corrosion Inhibitor N,n-dimethyl formamide Prevents the corrosion of the pipe Used in pharmaceuticals, acrylic fibers, plastics > Crosslinker Borate salts Maintains fluid viscosity as temperature increases Laundry detergents, hand soaps, and cosmetics > Friction Reducer > Polyacrylamide > > Mineral oil > Minimizes friction between the fluid and the pipe > Water treatment, soil conditioner > > make-up remover, laxatives, and candy > Gel Guar gum or hydroxyethyl cellulose Thickens the water in order to suspend the sand Cosmetics, toothpaste, sauces, baked goods, ice cream > Iron Control Citric acid Prevents precipitation of metal oxides Food additive, flavoring in food and beverages; Lemon Juice ~7% Citric Acid > KCI Potassium chloride Creates a brine carrier fluid Low sodium table salt substitute > Oxygen Scavenger Ammonium bisulfite Removes oxygen from the water to protect the pipe from corrosion Cosmetics, food and beverage processing, water treatment > pH Adjusting Agent Sodium or potassium carbonate Maintains the effectiveness of other components, such as crosslinkers Washing soda, detergents, soap, water softener, glass and ceramics > Proppant Silica, quartz sand Allows the fractures to remain open so the gas can escape Drinking water filtration, play sand, concrete, brick mortar > Scale Inhibitor Ethylene glycol Prevents scale deposits in the pipe Automotive antifreeze, household cleansers, and deicing agent > Surfactant Isopropanol Used to increase the viscosity of the fracture fluid Glass cleaner, antiperspirant, and hair color > Note: The specific compounds used in a given fracturing operation will vary depending on company preference, source water quality and site-specific characteristics of the target formation. The compounds shown above are representative of the major compounds used in hydraulic fracturing of gas shales. >
Link #1
Link #2
Attach file
Type the letters shown in the left box..